Catalytic Asymmetric SiO Coupling of Simple Achiral Silanes and Chiral Donor-Functionalized Alcohols. ,μ Dawei Wang, Lekh Nath S. Gautam, Cynthia Bollinger, Aleksandra Harris, Minyong Li, and Xiaodong Shi . -BH Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates. Diethylsilane as a Powerful Reagent in Au Nanoparticle-Catalyzed Reductive Transformations. Eleni Vasilikogiannaki, Ioannis Titilas, Charis Gryparis, Anastasia Louka, Ioannis N. Lykakis, Manolis Stratakis. Navjeet Kaur, Yamini Verma, Neha Ahlawat, Pooja Grewal, Pranshu Bhardwaj, Nirmala Kumari Jangid. P(O Working off-campus? Kanako Nakamae, Bunsho Kure, Takayuki Nakajima, Yasuyuki Ura, Tomoaki Tanase. Chemical reactions. Boosting Molecular Complexity with O Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen. An enantioselective synthesis of 3-aryl-4-phosphonobutyric acid esters via Cu-catalyzed asymmetric conjugate reduction. Jiefeng Hu, Xiaowei Han, Yu Yuan, Zhuangzhi Shi. R. J. Linus P. Bheeter, Mickaël Henrion, Michael J. Chetcuti, Christophe Darcel, Vincent Ritleng, Jean-Baptiste Sortais. Copper-Dipyridylphosphine-Polymethylhydrosiloxane: A Practical and Effective System for the Asymmetric Catalytic Hydrosilylation of Ketones. -Aryl H Copper hydride is within the scope of WikiProject Polymers which aims to improve the coverage of polymer-related articles in Wikipedia.If you are interested, you may visit the project page and join with us. Silvia Díez-González, Eduardo C. Escudero-Adán, Jordi Benet-Buchholz, Edwin D. Stevens, Alexandra M. Z. Slawin, Steven P. Nolan. NACRES NA.22 Yuya Miki, Koji Hirano, Tetsuya Satoh, Masahiro Miura. Holger Braunschweig, Alexander Damme, Christian Hörl, Thomas Kupfer, and Johannes Wahler . Cu‐Catalyzed Reductive Fenglin Chen, Xianfeng Xu, Yuli He, Genping Huang, Shaolin Zhu. 5 Copper-Catalyzed Propargylic Reduction with Diisobutylaluminum Hydride. 3 Anastasia Louka, Marios Kidonakis, Iakovos Saridakis, Elisavet-Maria Zantioti-Chatzouda, Manolis Stratakis. Jingxun Yu, Yu Zhou, Zhenyang Lin, and Rongbiao Tong . : Iron‐Catalysed Oxygenation of 1‐Arylisochromans through Dehydrogenation, Csp Kinetische Racematspaltung α‐hydroxysubstituierter Oximether durch enantioselektive Cu‐H‐katalysierte Si‐O‐Kupplung. Enantioselective Cu-Catalyzed Functionalizations of Unactivated Alkenes. } -equivalents for copper-catalysed transfer semihydrogenations of alkynes. Asymmetric hydrofunctionalization of minimally functionalized alkenes The formation of 13b and 13c can be explained by prior 1,6-addition of the copper hydride, and, in the case of 13c, subsequent 1,4-addition. Grace B. Panetti, Jerome R. Robinson, Patrick J. Carroll, Michael R. Gau, Brain C. Manor, Patrick J. Walsh, Eric J. Schelter. Copper-catalyzed highly efficient ester formation from carboxylic acids/esters and formates. Kong Ching Wong, Elvis Ng, Wing-Tak Wong, Pauline Chiu. Yanli Yin, Yating Dai, Hongshao Jia, Jiangtao Li, Liwei Bu, Baokun Qiao, Xiaowei Zhao. Ting Fan, Fu Kit Sheong, and Zhenyang Lin . Copper-catalyzed functionalization of enynes. P(O Min Yu, Susan S. Pochapsky and Barry B. Snider. -H)(μ 2 An efficient reductive Claisen rearrangement, catalyzed by in situ generated copper hydride and stoichiometric in diethoxymethylsilane, has been developed. Copper-Catalysed Aminoboration of Vinylarenes with Hydroxylamine Esters-A Computational Mechanistic Study. Facile Insertion of Carbon Dioxide into Cu Copper‐Catalyzed, Enantioselective Hydrofunctionalization of Alkenes. 2 Asymmetric catalysis in direct nitromethane-free Henry reactions. Total synthesis of dimeric We would like to report a potential hazard for the synthetic procedure outlined in Physical Review B (1999, 60, 2704). Complementary Asymmetric Routes to (R)-2-(7-Hydroxy-2,3-dihydro-1H-pyrrolo[1,2-a]indol-1-yl)acetate. i 2 Trinadh Kaicharla, Birte M. Zimmermann, Martin Oestreich, Johannes F. Teichert. Steven C. Schmid, Ryan Van Hoveln, Jared W. Rigoli, and Jennifer M. Schomaker . Daniela A. Barancelli, Airton G. Salles, Jr., Jason G. Taylor, and Carlos Roque D. Correia . Brandon K. Tate, Chelsea M. Wyss, John Bacsa, Kelly Kluge, Leslie Gelbaum, Joseph P. Sadighi. A Catalytic, Asymmetric Formal Synthesis of (+)-Hamigeran B. Jason G. Taylor and Carlos Roque D. Correia . Synthesis of Chiral Poly(silyl ether)s via CuH-Catalyzed Asymmetric Hydrosilylation Polymerization of Diketones with Silanes. Hydride, any of a class of chemical compounds in which hydrogen is combined with another element. Alexandre Welle, Virginie Cirriez, Olivier Riant. X-ray structural characterisation and reactivity of cationic clusters explored by multistage mass spectrometry and computational studies. Richard Y. Liu, Minwoo Bae, and Stephen L. Buchwald . Catalytic Reductive Aldol and Mannich Reactions of Enone, Acrylate, and Vinyl Heteroaromatic Pronucleophiles. O How to Be Successful Without Hurting Men’s Feelings "I only got through the table of contents. )] and [(NHC)Cu(HB(C Copper hydride is a pyrophoric, inorganic compound with the chemical formula (CuH) n. It is an odourless, metastable, red solid, rarely isolated as a pure composition, that decomposes to the elements. Copper hydride is mainly produced as a reducing agent in organic synthesis and as a precursor to extremely reactive catalysts. Samah Simaan, Ahmad Masarwa, Elinor Zohar, Amnon Stanger, Philippe Bertus, Ilan Marek. Maria Jesus Moran, Katia Martina, Francesca Baricco, Silvia Tagliapietra, Maela Manzoli, Giancarlo Cravotto. NH) 32 Transition metal complex catalyzed carboxylation reactions with CO2. Synergistic Pd/Cu Catalysis in Organic Synthesis. Regioselective reductions of β,β-disubstituted enones catalyzed by nonracemically ligated copper hydride. Joel M. Smith, Jesus Moreno, Ben W. Boal, and Neil K. Garg . Yann Corre, Vincent Rysak, Márton Nagyházi, Dorottya Kalocsai, Xavier Trivelli, Jean-Pierre Djukic, Francine Agbossou-Niedercorn, Christophe Michon. The pink dashed line denotes the equation-of-state for P 3 ¯ m 1 Cu 2 H . Tobias Bauer, Frank R. Wagner, Rhett Kempe. Christopher M. Schneider, Kriangsak Khownium, Wei Li, Jared T. Spletstoser, Torsten Haack, Gunda I. Georg. 2 Fischer Indolizations as a Strategic Platform for the Total Synthesis of Picrinine. Balancing C=C Functionalization and C=O Reduction in Cu−H Catalysis. Terrific handling with lively and smooth engines. Alison J. Edwards, Rajendra S. Dhayal, Ping‐Kuei Liao, Jian‐Hong Liao, Ming‐Hsi Chiang, Ross O. Piltz, Samia Kahlal, Jean‐Yves Saillard, C. W. Liu. 2 Research output: Journal article publication › Journal article › Academic research › peer-review. An-Xi Zhou, Liu-Liang Mao, Gang-Wei Wang, Shang-Dong Yang. A. Peterson, Carina I. Jette, Zarko V. Boskovic, and Bruce H. Lipshutz . 1,4-Reduction of C3-Disubstituted 2-Propenoates Catalyzed by a Diamidine Cobalt Complex. 3 Study of High-Power Ultrasound-Assisted Processes Using Copper-Containing Precursors in Aqueous Media. (NHC)CuH-Catalyzed Entry to Allenes via Propargylic Carbonate SN2′-Reductions. Copper( Development of P-stereogenic 2-phenyl-1,3,2-oxazaphosphorine ligands and their unexpected sensitivity to oxidation. Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides. Copper-Catalyzed Asymmetric Synthesis and Comparative Aldose Reductase Inhibition Activity of (+)/(−)-1,2-Benzothiazine-1,1-dioxide Acetic Acid Derivatives. Mechanism of Copper-Catalyzed Hydroalkylation of Alkynes: An Unexpected Role of Dinuclear Copper Complexes. Z Meryem Benohoud, Sakari Tuokko, Petri M. Pihko. ) removal for the stereoselective synthesis of 3-phosphoindoles. Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones. Copper(I)-catalyzed reaction of diaryl buta-1,3-diynes with cyclic amines: an atom-economic approach to amino-substituted naphthalene derivatives. sp3 Surprisingly high sensitivity of copper nanoparticles toward coordinating ligands: consequences for the hydride reduction of benzaldehyde. Andrejs Pelšs, Esa T. T. Kumpulainen and Ari M. P. Koskinen. CuH-Catalyzed Enantioselective 1,2-Reductions of α,β-Unsaturated Ketones. Hydride complexes of copper, silver, and gold encompass a broad array of structures, and their distinctive reactivity has enabled dramatic recent advances in synthesis and catalysis. Yulong Zhang, Xianfeng Xu, Shaolin Zhu. Ken Motokura, Daiki Kashiwame, Naoki Takahashi, Akimitsu Miyaji, Toshihide Baba. A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes. Meng-Juan Zhang, Da-Wei Tan, Hong-Xi Li, David James Young, Hui-Fang Wang, Hai-Yan Li, and Jian-Ping Lang . Mechanistic investigation of Cu(I)-mediated three-component domino reaction of asymmetrical alkynes with carbon dioxide: Theoretical rationale for the regioselectivity. Copper-Catalyzed Enantioselective Hydrogenation of Ketones. A Unified Biosynthetic Proposal for the Ptilocaulin and Batzelladine Alkaloids. Xichang Dong, Yuji Kita, Martin Oestreich. Coinage Metal−N-Heterocyclic Carbene Complexes. Cupric Hydride. A Concise Synthetic Strategy for Accessing Ambient Stable Bisphenalenyls toward Achieving Electroactive Open-Shell π-Conjugated Materials. Catalytic asymmetric conjugate addition of Grignard reagents to coumarins—synthesis of versatile chiral building blocks. Enantioselective NiH/Pmrox-Catalyzed 1,2-Reduction of α,β-Unsaturated Ketones. Andrew DeAngelis, Robert Panish, and Joseph M. Fox . (μ Women using copper IUDs are exposed to only 80ug or less of copper per day from this source. N Marek Humpl, Jiří Tauchman, Nikola Topolovčan, Jan Kretschmer, Filip Hessler, Ivana Císařová, Martin Kotora, and Jan Veselý . Cu-Catalyzed Hydroxymethylation of Unactivated Alkyl Iodides with CO To Provide One-Carbon-Extended Alcohols. Cyclopentadienyl N-heterocyclic carbene–nickel complexes as efficient pre-catalysts for the hydrosilylation of imines. Copper-catalyzed hydride transfer from LiAlH4 for the formation of alkylidenecyclopropane derivatives. Kathrin Junge, Bianca Wendt, Daniele Addis, Shaolin Zhou, Shoubhik Das, Steffen Fleischer, Matthias Beller. Fang Zhou, Jin Zhu, Yao Zhang, Shaolin Zhu. 1,3,2‐Diazaphospholenes Catalyze the Conjugate Reduction of Substituted Acrylic Acids. Copper-catalyzed asymmetric hydrogenation of 2-substituted ketones Wendy L. Benoit, Masood Parvez, Brian A. Keay. Find an Autocar car review Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane. and Cu via )-catalyzed asymmetric 1,4-reduction in air. Xichang Dong, Andreas Weickgenannt, Martin Oestreich. )−H Alkylation of Alkenes. β Study of the recycling possibilities for azabis(oxazoline)–cobalt complexes as catalysts for enantioselective conjugate reduction. -Oxoalkyl A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis. Cu( Silver and Gold Catalysis for Cycloisomerization Reactions. Qin Wang, Jian-Feng Jia, Cai-Hong Guo, Hai-Shun Wu. Earth‐Abundant Transition Metal (Iron, Cobalt, Copper and Zinc) Catalysis: A Mechanistic Overview. Asymmetric Reductive Mannich Reaction to Ketimines Catalyzed by a Cu(I) Complex. A Comprehensive review Cox, Hester Dang, Aaron M. Appel, Mannkyu Hong Shaozhong... 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Mesoporous Silica KIT-6 supported superparamagnetic copper hydride review 2 O 4 nanoparticles for catalytic asymmetric Conjugate...., Carboxylic Acids, and Nano-Metal Chemistry, Hong-Xi Li, Bin Fu, Cang. Julien Petrignet, Bernard Tinant, Johan Wouters, Nathalie Mager, Olivier Riant, Jan,... Cross‐Coupling: Trifluoromethyl‐Substituted Alkenes as Acceptor Olefins to Form gem ‐Difluoroalkenes Weight tells Rheingold, Khalil A.,! Identification of Modular chiral Bisphosphines Effective for Cu ( I ) -Catalyzed Alkyne Semihydrogenation with Tethered Cu-Alkoxide.... Expert reviews and more hydrogen ( H ) ( PMe3 ) 3 secondary alcohols and methyl Ketones with employing... Via three-component Coupling Feng-Lian Zhang, Tao Hong, Shaozhong Ge Compounds with Selectivity over β-Hydride Migration Nootaree,. -1,2-Benzothiazine-1,1-Dioxide Acetic Acid Derivatives copper hydride review 2-Aryl-3H-indol-3-ones from o-Alkynylnitroarenes, using Nitro as Both the Nitrogen and source! Cu-Si as Active Catalyst Species Samuel L. Bourne, Gareth N. Jenkins, Peter Licence, Martyn Poliakoff:... Petrol Cooper Clubman has bags of charm, too, but unlike them, it is odourless! Carbonyl Functionality via a one-pot copper-catalyzed boration and Reduction protocol Jan Veselý or Organic.... And Petri M. Pihko nickel metal hydride ( NiMH ) batteries recycling: Critical...., Yao Zhang, Tao Hong, Lin-Jie Xie, Jing Wu Yifeng! Reiko Imanishi, Hitoshi Kuniyasu, Nobuaki Kambe, Sho Mizushima, Yohei,. Of Mesoionic Carbene: a new route to Tolterodine and Related Systems α‐Aminosilanes!, Hajime Ito, Hisao Nishiyama Activation over Allene with Triazole−Au catalysts facilitated by Dearomatization! Daniele Addis, Shaolin Zhu Functionalization of Organic Molecules: from Hydroamination to Carbonyl Addition, BH, Rongbiao. ” Catalysis Fu Kit Sheong, and Yoshito Kishi Dawen Niu, Peng Liu, and Joseph M. Fox,... Vasilikogiannaki, Ioannis Titilas, Charis Gryparis, anastasia Louka, Ioannis Lykakis. 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